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ammonium nitrite : ウィキペディア英語版
ammonium nitrite

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Ammonium nitrite, NH4NO2, is the ammonia salt of nitrous acid. It is used as a rodenticide, microbiocide and agricultural pesticide, and is acutely toxic to both humans and aquatic organisms.〔(【引用サイトリンク】title=Ammonium nitrite - Identification, toxicity, use, water pollution potential, ecological toxicity and regulatory information )
==Preparation==
Ammonium nitrite forms naturally in the air and can be prepared by the absorption of equal parts nitrogen dioxide and nitric oxide upon aqueous ammonia.
It can also be prepared by oxidizing ammonia with ozone or hydrogen peroxide, or in a precipitation reaction of barium or lead nitrite with ammonium sulfate, or silver nitrite with ammonium chloride, or ammonium perchlorate with potassium nitrite. The precipitate is filtered off and the solution concentrated. It forms colorless crystals which are soluble in water and decompose on heating or in the presence of acid, with the formation of nitrogen. Ammonium nitrite solution is stable at higher pH and lower temperature. If there is any decrease in pH lower than 7.0, It may lead to explosion. It is desirable to maintain pH by adding ammonia solution. The mole ratio of Ammonium Nitrite to Ammonia must be above 10% mole ratio.
:NH4NO2 → N2 + 2 H2O

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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